A reversible two-electron redox system involving a divalent lead species.
نویسندگان
چکیده
Reduction of THF-stabilized plumbacyclopentadienylidene with lithium afforded dilithioplumbole. On the other hand, oxidation of the dilithioplumbole provided the starting plumbacyclopentadienylidene. This is the unprecedented example of a reversible interconversion between group 14 M(II) and its dianionic species bearing organic substituents.
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عنوان ژورنال:
- Chemical communications
دوره 51 22 شماره
صفحات -
تاریخ انتشار 2015